How does Cylinder Pressure relate to the octane rating of today's unleaded fuel?

In very basic terms, the more cylinder pressure we make the more power the engine will produce. But look out for the fuel! Today's pump gas is too volatile and cannot tolerate high compression ratio (above 10.5:1) and high cylinder pressure (above approximately 165 PSI) without risking detonation. Fuel octane boosters or expensive racing gasoline will be necessary if too much cylinder pressure is generated.